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氩氦射频感应耦合等离子体制备球形碳化硼粉末的数值模拟及实验研究

Numerical Simulation and Experimental Study on the Preparation of Spherical Boron Carbide Powder by Ar-He Radio Frequency Inductively Coupled Plasma

  • 摘要: 本文采用射频感应耦合等离子体(RF-ICP)开展对碳化硼(B4C)粉末球化的实验与模拟研究,在等离子体工作气体中加入不同含量的氦(He)的实验条件下,对比其 He掺杂对球化B4C粉末的表面形貌和粒径分布的影响,特别关注了对球化率的影响规律。同时结合三维数值模拟,分析了等离子体与粉末颗粒之间的相互作用,揭示了He的加入对等离子体热力学特性及等离子体-颗粒传热过程的影响机理。研究结果表明:在 RF-ICP 球化 B4C 粉末过程中,He 的加入能提升等离子体的热导率与比热容,从而在提高体系焓值的同时,也使滞留颗粒能够吸收更多的净热量。这不仅显著提升了B4C粉末的球化率,还提高等离子体能量利用率。本文研究结果对等离子体制备高质量B4C球形粉末具有重要的科学意义和参考。

     

    Abstract: This study investigates the spheroidization of boron carbide (B4C) powder using radiofrequency inductively coupled plasma (RF-ICP) through experimental and simulation approaches. Under experimental conditions involving varying concentrations of helium (He) added to the plasma working gas, the effects of He doping on the surface morphology and particle size distribution of spheroidized B4C powder are compared, with particular focus on the influence patterns on the spheroidization rate. Meanwhile, three-dimensional numerical simulations were coupled to analyze the interaction between plasma and powder particles, revealing the mechanism by which He addition influences the thermodynamic properties of the plasma and the plasma-particle heat transfer process. The results indicate that during the RF-ICP spheroidization of B4C powder, the addition of He not only enhances the thermal conductivity of the plasma but also increases its enthalpy by raising the specific heat capacity. This enables particles to absorb more net heat during their residence time in the plasma. Consequently, both the spheroidization rate of B4C powder and the energy utilization efficiency of the plasma are significantly improved. This study has important scientific significance and reference value for the plasma-based preparation of high-quality spherical B4C powder.

     

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