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原子层刻蚀:工艺、材料兼容性与应用研究进展

Atomic Layer Etching: Process, Material Compatibility and Advances in Applications

  • 摘要: 原子层刻蚀(Atomic Layer Etching,ALE)是一种基于“表面改性−刻蚀”循环机制的原子级精度材料去除技术,凭借其单层自限性、高选择性和三维均匀性,被广泛应用于半导体制造、纳米器件加工及光电子器件开发等领域。根据刻蚀过程所需能量来源不同,ALE技术主要分为热原子层刻蚀(T-ALE)、激光原子层刻蚀(L-ALE)、离子束原子层刻蚀(IB-ALE)和等离子体原子层刻蚀(P-ALE)。本文综述了各类ALE技术的基本原理、工艺特征及最新研究进展,重点探讨了等离子体原子层刻蚀(P-ALE)在硅基材料、氮化硅、氧化硅及过渡金属化合物等体系中的最新应用。同时,对比国内外发展现状,提出国内ALE技术有待突破多材料兼容性、工艺稳定性及环保前驱体开发等挑战。最后,本文展望了ALE技术的未来发展方向,包括激光−等离子体耦合工艺、机器学习驱动的智能化控制及低全球变暖潜能值(GWP)气体替代,为下一代原子级制造技术的研发与应用提供理论支撑。

     

    Abstract: Atomic layer etching (ALE) is a material removal technology with atomic-level precision based on a cyclic "surface modification-etching" process. Owing to the excellent performance including self-limiting monolayer removal, high selectivity, and three-dimensional uniformity, ALE has been extensively applied in semiconductor manufacturing, nanodevice processing, and optoelectronic device development, among other fields. Depending on energy-driven mechanisms, ALE technologies are primarily categorized into thermal atomic layer etching (T-ALE), laser atomic layer etching (L-ALE), ion beam atomic layer etching (IB-ALE) and plasma atomic layer etching (P-ALE). This review summarizes the fundamental principles, process characteristics, and recent advancements of various ALE technologies, with a focus on the latest applications of plasma atomic layer etching (P-ALE) in silicon-based materials, silicon nitride, silicon oxide, and transition metal compounds. Furthermore, in comparison to international developments, the review highlights challenges for domestic ALE technologies, including the need for breakthroughs in multi-material compatibility, process stability, and eco-friendly precursor development. Finally, the future development of ALE technique has been prospected, encompassing laser-plasma hybrid processes, machine learning-driven intelligent control, and low global warming potential gas alternatives, which provides theoretical support for the research and application of next-generation atomic-scale manufacturing technologies.

     

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