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多孔Ti基吸气剂的分子动力学仿真与性能表征

Molecular Dynamics Simulation and Verification of the Improvement of Getter Performance by Porous Scaffold

  • 摘要: 吸气剂对维持MEMS(Micro-Electro-Mechanical System)器件真空度起着至关重要的作用,目前常见的提升吸气剂性能的方法是在大比表面积的多孔支架上沉积吸气剂。为了验证多孔结构对提升吸气剂性能的突出作用,使用分子动力学仿真软件Lammps对薄膜型吸气剂和多孔支架吸气剂的吸附行为进行了仿真,仿真结果表明多孔支架吸气剂的吸气量是薄膜型吸气剂的2.69倍。使用磁控溅射法分别在硅和多孔镍支架表面沉积了一层Ti吸气剂,用热重法分别对两者的吸气性能做了测试,结果表明,多孔支架型吸气剂的吸气量(0.5961 mg )是薄膜型吸气剂(0.2829 mg)的2.11倍。采用定压法对两种类型的吸气剂分别做了定压法气体吸附试验,多孔镍支架Ti吸气剂的吸气容量(2.16×10−3 Pa∙ml/cm2)是薄膜型(6.74×10−4 Pa∙ml/cm2)的3.2倍。

     

    Abstract: Getters play a vital role in maintaining the vacuum of MEMS devices. Currently, a common method to improve the performance of getters is to deposit getters on porous scaffolds with large specific surface areas. In order to verify the significant role of porous structure in improving getter performance, the molecular dynamics simulation software Lammps was used to simulate the adsorption behavior of thin film getters and getters with porous scaffolds. The simulation results show that the adsorption capacity of the getter with a porous scaffold is 2.69 times that of the thin film getter. A layer of Ti getter was deposited on the surface of silicon and porous nickel scaffolds using the magnetron sputtering method, and the adsorption capacity of both was tested using the thermogravimetric method. The results show that the adsorption amount of the getter with porous nickel scaffold (0.5961 mg) is 2.11 times that of the thin film getter (0.2829 mg). Gas adsorption tests were conducted on the two types of getters using the constant pressure method. The getter capacity of the Ti getter with porous nickel scaffold (2.16×10−3 Pa∙ml/cm2) is 3.2 times that of the thin film Ti getter (6.74×10−4 Pa∙ml/cm2).

     

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