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基于氢氧催化键合的石英光学真空腔体低温封装工艺研究

Low-Temperature Packaging Process of Quartz Optical Vacuum Cavities with Hydroxide-Catalysis Bonding

  • 摘要: 文章提出了一种基于氢氧催化键合技术制作小型光学石英真空腔体的低温封装工艺。通过预实验探讨了键合溶液、固化温度、稳定时间等因素对石英玻璃键合的影响,优选出一套当前实验条件下的最佳键合方案。研究表明,两种实验浓度下的Na2SiO3溶液键合强度普遍高于NaOH;1:6的Na2SiO3溶液键合在80℃下加速固化能够实现不低于12 MPa的抗拉强度,并将固化时间缩短至1天;Na2SiO3溶液键合的稳定时间比NaOH溶液更短,大概只有30 s但这也足够完成某些应用的对准操作。基于优化方案设计并制作出一种双面通光石英光学真空腔体,测试表明其整体漏率优于5.66×10−12 Pa·m3·s−1并且热稳定性良好。本研究可以为小型化的石英光学真空腔体的制造提供了一种低成本、工艺简单且性能优越的可行方案。

     

    Abstract: This paper presents a low-temperature process for fabricating compact optical quartz vacuum cavities based on hydroxide-catalysis bonding technology. This study conducted pre-experiments to investigate the effects of bonding solution, curing temperature, setting time on the bonding of quartz glass, and optimized a set of optimal bonding schemes for the current experimental conditions. The study showed that the bonding strength of Na2SiO3 solution at both concentrations was generally higher than that of NaOH; 1:6 Na2SiO3 solution bonding with accelerated curing at 80℃ was able to achieve a tensile strength of not less than 12 MPa and shortened the curing time to 1 day. The setting time of Na2SiO3 solution bonding is shorter than NaOH solution, probably only 30 s but sufficient for some applications. A quartz optical vacuum cavity was designed and successfully fabricated according to this scheme, showing that the overall leakage rate was better than 5.66×10−12 Pa·m3·s−1 and good thermal stability after thermal cycling tests. This study provides a feasible solution for the fabrication of a compact quartz glass optical vacuum cavity with low cost, simple process and excellent performance.

     

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