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面向水平GAA内侧墙模块的干法Si0.7Ge0.3选择性刻蚀研究

Dry Selective Etching of Si0.7Ge0.3 for Horizontal GAA Inner Spacer Module

  • 摘要: 针对环栅(Gate-All-Around,GAA) Si0.7Ge0.3的内侧墙(Inner spacer)空腔刻蚀难以精确控制尺寸和形貌的问题,本研究基于常规电感耦合等离子体(inductively coupled plasma,ICP)刻蚀设备,采用CF4/O2/He混合气体进行Si0.7Ge0.3干法各向同性选择性刻蚀实验,探究了包括激励射频源(source radio frequency,SRF)功率、气压、刻蚀前侧壁清洗工艺等因素对刻蚀结果的影响与机制。研究结果表明,SRF对刻蚀深度的影响是存在线性区与准饱和区的,气压与刻蚀深度在实验区间内呈二次函数关系,稀释的氢氟酸(Diluted HF,DHF)与O3交替清洗相对单一的DHF清洗方案在界面钝化层的去除与刻蚀形貌的控制上有更优的表现。经工艺方案优化,最终获得良好的工艺结果:刻蚀精度达到了0.61 nm/s,最优粗糙度Rq为0.101 nm,刻蚀轮廓矩形度高(d/t~83.3%)。本研究为内侧墙空腔刻蚀提供了一种解决方案。

     

    Abstract: Aiming at the issue that it is difficult to accurately control the size and profile of the inner spacer cavity etching of Si0.7Ge0.3 in Gate-All-Around (GAA) process flow, based on the conventional inductively coupled plasma (ICP) etching tool, dry isotropic selective etching experiment of Si0.7Ge0.3 was carried out with CF4/O2/He mixed gas. The effects and mechanisms of factors such as the power of SRF (source radio frequency), gas pressure, and the sidewall cleaning process before etching were explored. The results show that there are linear and quasi-saturated regions in the effect of SRF on the etching rate, and there is a quadratic function relationship between gas pressure and etching rate in the experimental range. Diluted HF (DHF) and O3 alternate cycle cleaning process has a better performance than the single DHF cleaning in the removal of the interface passivation layer and the control of the etching profile. After the optimization of the process scheme, better process results are obtained: the etching accuracy reaches 0.61 nm/s, the optimal roughness Rq is 0.101 nm, and the rectangle of the etching profile is high (d/t~83.3%). This study provides a solution for the inner spacer cavity etching.

     

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