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衬底温度对氢化非晶氧化硅(i-a-SiOx:H)钝化 性能的影响研究

Effect of Substrate Temperature on Passivation Properties of Hydrogenated Amorphous Silicon Oxide (i-a-SiOx:H)

  • 摘要: 本征氢化非晶氧化硅(i-a-SiOx:H)是a-Si:H/c-Si异质结太阳电池中重要的钝化材料之一。本文采用PECVD法研究不同沉积衬底温度下n-Cz-Si表面沉积i-a-SiOx:H的钝化性能,采用微波光电导(MW-PCD)和射频光电导(RF-PCD)两种方法测试硅片少子寿命,光谱型椭偏仪检验沉积薄膜的晶型。结果表明:(1)椭偏仪结果显示实验所沉积薄膜为所需非晶型;(2)MW-PCD与RF-PCD法测试均显示,n-Cz-Si双面室温(25℃)沉积i-a-SiOx:H后硅片少子寿命很低,随沉积衬底温度升高硅片少子寿命先增加后减少,25℃少子寿命最低,200℃~220℃(不同位置略有差别)少子寿命最高、钝化效果最优。

     

    Abstract: Intrinsic hydrogenated amorphous silicon oxide (i-a-SiOx:H) is one of the important passivation materials in a-Si: H/c-Si heterojunction solar cells. In this paper, the passivation properties of i-a-SiOx:H deposited on the surface of n-Cz-Si at different substrate temperatures were studied by PECVD. The minority carrier lifetime of silicon wafers was measured by microwave photo-conductivity (MW-PCD) and radio frequency photo-conductivity (RF-PCD). The crystal form of the deposited films was examined by spectroscopic ellipsometry. The results show that: (1) the ellipsometer results show that the deposited films are amorphous; (2) MW-PCD and RF-PCD tests show that the minority carrier lifetime of the silicon wafer is very low after i-a-SiOx:H deposited on both sides of n-Cz-Si at room temperature. With the increase of deposition substrate temperature, the minority carrier lifetime of the silicon wafer increases first and then decreases, and the passivation effect is optimal at 200℃~ 220℃.

     

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