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脉冲调制射频大气压SiH4/He/O2放电数值模拟研究

Numerical Simulation of Pulse-Modulation Radio-Frequency Atmospheric-Pressure SiH4/He/O2 Discharge

  • 摘要: 大气压等离子体放电由于设备简单,生产成本低,一直被广泛用于二氧化硅薄膜沉积中。较其他形式的放电,大气压脉冲放电由于其稳定、高效等特点在近年来引起了人们的广泛关注。为了更深入了解其反应机理,本文利用二维流体力学模型对脉冲调制射频大气压SiH4/He/O2的放电过程进行了研究,重点关注了脉冲放电中占空比与调制频率对等离子体的影响。结果表明:在平均功率相同的条件下,占空比对薄膜的沉积速率和质量具有重要影响。具体表现为,随着占空比减小,反应腔中各粒子密度均呈现出增加的趋势,且当占空比为0.4时,SiO2密度约为1014 cm-3,高于连续放电三个数量级;同时电场对负离子的约束作用也随着占空比的减小而减弱,导致大量的负离子流向极板,形成了对薄膜的性能有益的负离子流;另外适当降低占空比还可以改善薄膜的均匀性。值得注意的是,适当降低调制频率也可以在不影响薄膜均匀性的情况下,提高薄膜沉积速率、改善薄膜附着性能,但其影响不如占空比显著。

     

    Abstract: Atmospheric-pressure plasma discharge has been widely used in silicon dioxide film deposition because of its simple equipment and low production cost. Compare to other kinds of discharges, atmospheric pressure pulse discharge attracts more attention because of its stability and high efficiency. In order to better understand the reaction mechanism, a two-dimensional hydrodynamics model is established to study the pulsed radio-frequency atmospheric pressure SiH4/He/O2 discharge, focusing on the effects of the duty ratio and modulation frequency on the plasma parameters in pulse discharge. The results show that the duty ratio has a significant impact on the deposition rate and film quality under the same power. The density of each particle in the reaction cavity decreases with the duty ratio, and the density of SiO2 reaches 1014 cm-3 when the duty ratio is 0.4, which is three orders of magnitude higher than that of continuous discharge. Meanwhile, the restriction of electric field on the negative ion is weakened when the duty ratio decreases, and a large number of negative ions flow to the wall of the device, thus a negative ion flow which has a significant impact on the surface treatment of the material is formed. In addition, properly reducing duty ratio can improve the uniformity of thin films. Noticeable, appropriately reducing the modulation frequency can also increase the film deposition rate and improve the film adhesion property without affecting the film uniformity, but its influence is far less than that of duty ratio.

     

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