Abstract:
A two-dimensional fluid model is developed to study the radio-frequency atmospheric-pressure Ar/O
2/SiH
4 discharges.The effect of gas composition on the densities of precursor particles and the uniformity of silicon dioxide film is emphasized.The simulation results show that the content of O
2 plays a decisive role in the whole discharge system.When the content of SiH
4 is constant,increasing the contents of O
2 can greatly increases the deposition rate and optimizes the uniformity of the film without changing the electron density.Although SiH
4 content significantly influencing the density of SiH
3O,it has little effect on the film properties.Note,when O
2 content is equal to SiH
4,the formation channel of SiH
3O particles is dominant and its density is high.When O
2 content is greater than SiH
4,SiH
2O generation channel will be dominate and its density is greater than that of SiH
3O.Meanwhile,the density of SiO
2 increases greatly,and it can reach 10
17 cm
-3.Therefore,in the actual industrial preparation of largearea films,increasing the O
2 content is helpful to obtain high deposition rate and high quality films.