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建筑用2524铝合金表面Al2O3/MAO膜组织及摩擦性能分析

Surface Modification of 2524 Al-Alloy with Al2O3 Coatings Synthesized by Micro Arc Oxidation

  • 摘要: 选择微弧氧化工艺并将氧化铝颗粒添加到电解液内,在建筑用22524铝合金基体上制得的微弧氧化膜。并通过实验测试的方式分析其组织及摩擦性能。研究结果表明:加入Al2O3能够使氧化膜内形成更多的陶瓷氧化物,可以获得更加致密的氧化膜组织。在MAO膜内加入Al2O3颗粒后含有O、Ti、Al、Si,Al2O3对电解液的微弧氧化过程发挥着关键作用。在加入Al2O3颗粒MAO膜厚度更大,提高MAO膜的致密度,产生更厚的致密组织。采用微弧氧化处理可以获得更大的硬度,其中硬度最大的是Al2O3加入量3 g/L试样。加入Al2O3的MAO膜形成了宽度较小的磨痕,也没有出现沟壑,只发生了较轻程度的磨损,经过磨损处理后,试样表面区域并未产生显著区别。

     

    Abstract: The surfaces of 2524 Al-alloy,an advanced door & window frame-material,were modified with Al2O3-coatings synthesized by micro-arc oxidation(MAO).The influence of the Al2O3 powder,added into the electrolyte,on the microstructures and tribological properties was investigated with X-ray diffraction,scanning electron microscopy,energy dispersive spectroscopy and conventional mechanical probes.The results show that the addition of Al2O3 powder significantly improved the quality of MAO Al2O3 coatings.To be specific,the smoother and more compact MAO Al2O3 coatings,comprising more α-and γ-phased Al2O3 grains,and lower density of pores and micro-cracks.The MAO Al2O3 coatings,31.2μm in thickness,have a hardness of 510 HV,a stronger wear-resistance and a lower average friction coefficient(0.45).Possible mechanisms responsible for the quality improvement of MAO coatings,grown in Al2O3-powder added electrolyte,were also tentatively discussed in a thought provoking way.

     

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