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真空电阻炉退火温度对电子设备用Ti-51Ni记忆合金相变和形状行为的影响

Effect of Annealing Temperature on Properties of Shape-Memory Ti-51Ni Alloy:An Experimental Study

  • 摘要: 选择电子设备用Ti-51Ni形状记忆合金作为测试材料,分析不同退火条件下Ti-51Ni合金形成的显微结构、相变特征及其超弹性变化情况。研究结果表明:在退火态Ti-51Ni合金中包含了r相以及马氏体m相。较低退火温度下合金中形成了具有纤维特征组织,较高退火温度下在合金中存在众多的尺寸较小的等轴晶结构。合金中的马氏体组织发生正、逆相变过程的峰值温度先上升后下降,合金中的r相组织发生正、逆相变过程的峰值温度单调下降。为了提高Ti-51Ni合金的力学强度,应在300~400℃范围内对其进行退火处理;如果需要提高Ti-51Ni合金的塑性,需将退火温度设定在500~600℃之间。随着温度继续上升接近马氏体的相变温度时,MR发生快速减小,从而引起逆马氏体相变的过程。当退火温度上升后,残余应发生了先减小后增大的现象。

     

    Abstract: The influence of the annealing temperature on the microstructures,phase transitions and super-elasticity of Ti-51 Ni shape-memory alloy,an advanced material for electronic devices,was investigated.The results show that the annealing temperature had a major impact.For instance,after annealing,the Ti-51 Ni alloy comprised r-phase and martensite phase.Textured fiber and equiaxed crystalline grains formed at low and high annealing temperatures,respectively.When it comes to transformation and inverse transformation,the peak temperature for martensite phase changed in an increase-decrease way,whereas the peak temperature for R-phase decreased monotonically.Annealing in 300~400℃ range increased the mechanical strength,and annealing in 500~600℃ range increased the plasticity.As the annealing temperature approached to the transformation temperature,the magnetoresistance decreased sharply,accompanied by the transformation.As the annealing temperature increased,the residual strain changed in a decrease-increase.

     

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