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ICP-CVD设备低温制备低应力氮化硅薄膜工艺的探索

Synthesis of Low Stress Silicon Nitride Thin Films at 80℃ by Inductively Coupled Plasma Chemical Deposition

  • 摘要: 制备低应力的氮化硅薄膜是微机械系统和集成电路中非常重要的工艺。在温度不高于80℃的条件下,采用ICP-CVD设备,利用硅烷和氮气作为前驱体沉积氮化硅介质薄膜。研究了沉积温度、ICP功率、硅烷与氮气流量比例、工作气压等因素对氮化硅薄膜应力的影响,并利用相关的理论合理解释了应力随不同工艺参数变化的原因。根据研究结果,我们优化了氮化硅薄膜沉积的工艺参数,在70℃低温条件下,制备出厚度160 nm,应力0.03 MPa的低应力氮化硅介质薄膜。

     

    Abstract: The low stress silicon nitride thin films were synthesized at a temperature below 80℃ by inductively coupled plasma chemical vapor deposition(ICP-CVD).The influence of the synthesis conditions,including the pressure,deposition temperature,ICP power and ratio of SiH4/N2 flow-rates,on the stress distribution of silicon nitride thin films was investigated.The results show that the growth conditions all had a major impact.For example,as the flow rate ratio increased,the stress changed in a decrease-increase mode.Under the optimized deposition conditions,the silicon nitride dielectric thin films were grown at 70℃ with a stress of 0.03 MPa and a thickness of 160 nm.The possible mechanism(s) responsible for the influence of a specific growth condition on the stress were tentatively discussed in a thought provoking way.

     

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