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CHEN Changhong, WANG Meifang, SUN Yijun, SUN Ying, SUN Jiabao, LIU Yanhua, LIU Zhi, XIE Shijian. Operation Parameters of Inductively Coupled C4F6/SF6 Plasma Etching Process for Si Substrate Material[J]. CHINESE JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY, 2023, 43(1): 36-41. DOI: 10.13922/j.cnki.cjvst.202207018
Citation: CHEN Changhong, WANG Meifang, SUN Yijun, SUN Ying, SUN Jiabao, LIU Yanhua, LIU Zhi, XIE Shijian. Operation Parameters of Inductively Coupled C4F6/SF6 Plasma Etching Process for Si Substrate Material[J]. CHINESE JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY, 2023, 43(1): 36-41. DOI: 10.13922/j.cnki.cjvst.202207018

Operation Parameters of Inductively Coupled C4F6/SF6 Plasma Etching Process for Si Substrate Material

  • To avoid the scallop effect caused by Bosch etching process and reduce GWPs carried by etching gas, an environmentally friendly electronic etching gas, C4F6, is introduced into the etching process. The Si substrate was etched by using a pseudo-Bosch process with simultaneous etching and passivation. And the effects of ICP power, RIE power, cavity pressure and flow rate of C4F6/SF6 on etching rate, photoresist/Si etch selection ratio and etch morphology were investigated. The results show that increasing ICP power and RIE power can improve the plasma density and physical bombardment effect, respectively; the chamber pressure has a large impact on the mean free diameter of particles, and the increase of C4F6 flux could strengthen the sidewall protection mechanism. Under the optimized etching condition, flat sidewalls, smooth surface, and high perpendicularity etching profile with 2.8 μm/min silicon etching rate and 3.1 photoresist/Si etching selection ratio can be obtained.
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