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不同温度下真空绝热板放气特性及扩散模型拟合的研究

Outgassing Characteristics and Diffusion Model Fitting of Vacuum Insulation Panels at Different Temperatures

  • 摘要: 真空绝热板(VIPs)的绝热性能依赖于其内部的高真空环境,其主要由芯材、阻隔膜、吸气剂及干燥剂组成,在实际应用中,芯材和阻隔膜的放气行为会导致真空度下降,进而影响其长期稳定性。温度是影响材料放气特性的关键因素,本研究通过实验测试不同温度(−15℃-70℃)下VIPs的放气特性,利用质谱分析气体成分并计算放气速率,基于复合材料的扩散放气理论模型,通过对实验数据进行拟合,建立了描述真空绝热板放气速率随时间变化的数学关系式。实验结果表明,随着温度升高,VIPs的放气速率越高,但是温度对VIPs的放气成分几乎没有影响,其中水蒸气(H2O)和氮气(N2)是主要释放气体;低温环境下放气速率较低,但仍存在长期缓慢释放现象。研究结果可为VIPs的吸气剂优化及寿命预测提供理论依据,并指导其在不同温度环境下的应用。

     

    Abstract: The thermal insulation performance of vacuum insulation panels (VIPs) relies on the high vacuum environment inside them, which is primarily composed of a core material, barrier film, getter, and desiccant. In practical applications, the outgassing behavior of the core material and barrier film can lead to a decline in vacuum level, thereby affecting their long-term stability. Temperature is a key factor influencing the outgassing characteristics of materials. In this study, the outgassing behavior of VIPs at different temperatures (−15°C to 70°C) was experimentally tested. The gas composition was analyzed using mass spectrometry, and the outgassing rate was calculated. Based on a composite material diffusion outgassing model, experimental data were fitted to establish a mathematical expression for the relationship between the outgassing rate of VIPs and time. The experimental results demonstrate that a rise in temperature can remarkably accelerate the outgassing process, whereas temperature exerts a negligible influence on the composition of gases released from the VIPs. Water vapor (H2O) and nitrogen (N2) are the main gases released. At low temperatures, the outgassing rate is lower, but slow release still occurs over time. The results offer a theoretical foundation for the optimization of desiccants in vacuum insulation panels (VIPs) and the prediction of their service life, while also providing guidance for their application in diverse temperature environments.

     

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